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Collaborators:

Dr. Shahriar Sajjadi, King's College London

Dr. Ankur Chaurusia

Mr. Tej  Singh 

Ms. Tanya Anthonypillay

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Energy intensive emulsification:

Investigated shear intensive emulsification method and how droplet deform and break-up under shear.

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Viscosity effect on drop formation

Low energy emulsification-The Ouzo effect:

Spontaneous droplet formation occurs by changing thermodynamic variation.

One approach is to change the solubility of phases. This can be achieved by using a solvent which has a higher affinity toward one phase. These can be shown in ternary phase diagrams. by changing the composition in a way to get a final composition in two-phase region, droplets can be formed through local super-saturation.

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Ternary phase diagram for spontaneous emulsification

Low energy emulsification-Phase inversion:

Spontaneous droplet formation occurs by changing thermodynamic variation.

Another approach is based on using surfactant as the third phase. A nano-dispersion with narrow size distribution forms when a gradual change in thermodynamic variation (temperature, composition) forms a single phase micellar solution (i.e., lamellar or cubic phase). A rapid deviation from this single phase system, forms local excess oil, forming droplets.

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Narrow droplet size distribution of phase inversion emulsification

Microfluidics:

Microfluidics have shown a great potential in forming droplets with low dispersity. I have investigated droplet formation and detachment process in microfluidics. As part of the research I developed a platform for producing nano-droplets within microfluidics and preparing results for publication.

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